; Li, X.-N., Temperature-programmed retention indices for gas chromatography-mass spectroscopy analysis of plant essential oils, J. Chromatogr. ; Fang H.Z. Group 1 Elements. Stable. 1,10-Phenanthroline (phen) is a heterocyclic organic compound. and Castellano, F.N. Each point on the graph represents mean SD (n = 3 . Incompatible with strong oxidizing agents. /Contents 4 0 R Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) with formula C14H10, consisting of three fused benzene rings. According to the accumulated data, denbinobin, with a novel mechanism of action, has great potential as a lead compound for the development of a new anticancer agent. Anthracene is a solid polycyclic aromatic hydrocarbon (PAH) of formula C 14 H 10, consisting of three fused benzene rings. Phenanthrene is generally used for dye production, synthetic resin, preservative. ; Kerr, A.A.; Lockington, J.N. [3], Phenanthrene occurs naturally and also is a man-made chemical. Bethesda, MD 20894, Web Policies Jmol.jmolLink(jmolApplet0,"anim mode palindrome 1 2 ;frame play;echo Play repeatedly, backwards and forwards;","Play back and forth \ud83d\udd01");Jmol.jmolBr() /Contents 6 0 R Caesium Peroxide Cs 2 O 2; Dipotassium Pentasulfide (K 2 S 5) Lithium nitride (Li 3 N) Na 172 In 192 Pt 2; K 4 Ge 4 [Cs(18-crown-6) 2] + e - Group 2 Elements. ; Vilegas, W., Identification of polycyclic aromatic hydrocarbons in sugar cane soot by gas chromatography-mass spectrometry, Chromatographia, 46(11/12), 1997, 655-663. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 25 m; Column type: Capillary; Heat rate: 8 K/min; Start T: 50 C; End T: 250 C; End time: 12 min; Start time: 2 min; CAS no: 85018; Active phase: SE-54; Carrier gas: He; Data type: Normal alkane RI; Authors: Harland, B.J. Please sign in to view account pricing and product availability. Because of its hydrophilic nature, it exhibits delayed transport across the blood-brain barrier, thus delaying its onset of action. Melting Point (C) Physical Form. Subcellular distribution and biotransformation of phenanthrene in pakchoi after inoculation with endophytic Pseudomonas sp. ; Hua, R.L. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Aquat. endobj Soluble in Ether,Benzene,Chloroform,Toluene. The 1,10 refer to the location of the nitrogen atoms that replace CH's in the hydrocarbon called phenanthrene. Symmetry point group: C 2v: Symmetry elements E C 2 (z) &sigma v (xz) &sigma v (yz) Irriducible representation &Gamma 3N: 24 A 1 + 12 A 2 + 24 B 1 + 12 B 2: Irriducible representation &Gamma vib: 23 A 1 + 11 A 2 + 22 B 1 + 10 B 2: Agency. [3] analysis of coal- and petroleum-derived liquid fuels, Fuel, 74(10), 1995, 1436-1451. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 310 C; Start time: 5 min; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B., Chapter 7. Special Grade. The .gov means its official. /Type/Page ; Buxaderas, S.; Lopez-Tamames, E., Simultaneous determination of volatile and semi-volatile aromatic hydrocarbons in virgin olive oil by headspace solid-phase microextraction coupled to gas chromatography/mass spectrometry, J. Chromatogr. 447 (1998) 163-215, Frenkel, M; Marsh, K.N. 2022;22(11):939-956. doi: 10.2174/1568026621666210813113918. 2023 Feb 9;15(4):883. doi: 10.3390/nu15040883. Phenanthrene can also be obtained photochemically from certain diarylethenes. There are 2 triclinic point groups: 1: Point group 1 has no symmetry operations besides the trivial 360 rotation from (X, Y, Z) to exactly the same (X, Y, Z). ; Silva, M.R.S. . Response Recommendations What is this information? Journals | Phenanthrenes: A Promising Group of Plant Secondary Metabolites Although phenanthrenes are considered to constitute a relatively small group of natural products, discovering new phenanthrene derivatives and evaluating their prospective biological activities have become of great interest to many research groups worldwide. 1996, 100, 15358-15367, M Gussoni, R Rui, G Zerbi "Electronic and relaxation contribution to linear molecular polarizability. Chromatogr., 173, 1979, 109-118. ass: Semi-standard non-polar; Column diameter: 0.28 mm; Column length: 12 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 50 C; End T: 250 C; CAS no: 85018; Active phase: SE-52; Carrier gas: He; Phase thickness: 0.17 um; Data type: Linear RI; Authors: Lee, M.L. Instrumental Anal., 15(4), 1999, 288-292. ass: Standard non-polar; Column type: Other; CAS no: 85018; Active phase: Methyl Silicone; Data type: Normal alkane RI; Authors: Ardrey, R.E. Polycyclic aromatic hydrocarbon composed of three fused benzene rings, InChI=1S/C14H10/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13/h1-10H, InChI=1/C14H10/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13/h1-10H, Except where otherwise noted, data are given for materials in their, Peter Atkins, J. D. P., Atkins' Physical Chemistry. /Group << /S /Transparency /CS /DeviceRGB /I false /K false >> Disclaimer, Copyright 2023 ChemSrc All Rights Reserved. Chromatogr., 12, 1989, 327-332. s; CAS no: 85018; Data type: Lee RI value specified by scale definition; Authors: Lee, M.L. Natural phenanthrenes and their biological activity. w !1AQaq"2B #3Rbr ; Zhao, C.-X. A, 774, 1997, 321-332. ass: Semi-standard non-polar; Column diameter: 0.50 mm; Column length: 16.6 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 50 C; End T: 320 C; Start time: 5 min; CAS no: 85018; Active phase: SE-52; Carrier gas: He; Data type: Linear RI; Authors: Beernaert, H., Gas Chromatographic Analysis of Polyclylic Aromatic Hydrocarbons, J. Jmol.jmolLink(jmolApplet0,"Frame Next","Next \u23ED");Jmol.jmolHtml('    ');Jmol.jmolLink(jmolApplet0,"Frame Prev","Prev \u23EE"); Anthracene is colorless but exhibits a blue (400-500 nm peak) fluorescence under ultraviolet radiation. Phenanthrene is nearly insoluble in water but is soluble in most low polarity organic solvents such as toluene, carbon tetrachloride, ether, chloroform, acetic acid and benzene. ; Sun, K.-J. Comm., 5, 1982, 325-328. umn class: Standard polar; Column diameter: 0.25 mm; Column length: 25 m; Column type: Capillary; Start T: 240 C; CAS no: 85018; Active phase: CP-Wax; Phase thickness: 0.22 um; Data type: Kovats RI; Authors: Hanai, T.; Hong, C., Structure-retention correlation in CGC, J. Hi. InChI=1S/C14H10/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13/h1-10H, CSID:970, http://www.chemspider.com/Chemical-Structure.970.html (accessed 14:45, Apr 18, 2023), Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agencys EPISuite, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the. Temperature (K) A B C Reference Comment; 373. [1]. ; Li, X.N. J. Environ. [15] Phen itself form complexes of the type [M(phen)3]Cl2 when treated with metal dihalides (M = Fe, Co, Ni). The infrared (IR) spectra were recorded on Shimadzu FT-IR . ; White, C.M. ChemTube3D by Nick Greeves is licensed under a Creative Commons Attribution-Noncommercial-Share Alike 2.0 UK: England & Wales License, Organic Chemistry Animations Introduction, Acid Chloride Formation Thionyl Chloride, Acid chloride formation-Phosphorus Pentachloride, Addition to C=O - loss of carbonyl oxygen, Molecules with a Plane of Symmetry Feists Acid, Chiral Allenes Without Stereogenic Centres, Conformations of ethane Newman projection, Conformational Analysis Pea Moth Pheromone, Substrate structure controls substitution mechanism S, E2 Regioselective Elimination to Menthenes A, E2 Regioselective Elimination to Menthenes B, Formation of Diazonium Salt Diazotization, Benzyne formation Diazotization-decarboxylation, Enolisation and formation of syn aldol product, Enolisation and formation of anti aldol product, Simple Diastereoselectivity - cis gives syn aldol, Simple Diastereoselectivity - trans gives anti aldol, Conjugate Addition of MeSH to an Unsaturated Aldehyde, Conjugate Addition of Diethylamine to an Unsaturated Nitrile (Acrylonitrile), Conjugate Addition of Diethylamine to an Unsaturated Ester, Conjugate Addition of Enamine to Unsaturated Imine, Conjugate addition of peroxide to form epoxides, Regioselectivity 2-methoxybuta-1,3-diene and acrylonitrile, Regioselectivity 1,1-dimethylbutadiene and methyl acrylate, Stereochemistry of the dienophile - diesters, Stereochemistry of the dienophile - dinitrile, The Woodward Hoffman description of the Diels-Alder, Intramolecular Diels-Alder (E)-3-Methyldeca-1,3,9-triene, Intramolecular Diels-Alder 1,3,9-decatrien-8-one, 2,3-Dimethylbutadiene and Acrolein(propenal), Quinone as Dienophile Steroid Framework, Intramolecular Diels-Alder Regioselectivity reversal, 8-Phenylmenthol auxiliary-controlled Diels-Alder, Paal-Knorr pyrrole synthesis via hemiaminal, Pyridine N-Oxide Nucleophilic Substitution, Pyridine N-Oxide Remote Oxidation And Rearrangement, 1,3-Dipolar Cycloaddition Isoxazole from nitrile oxide, Electrocyclic reactions are stereospecific, Conrotatory ring closure/opening - cyclobutene, Disrotatory ring closure/opening - hextriene, Semipinacol rearrangements of diazonium salts, Rearrangements with different nucleophiles, Retention of stereochemistry can indicate neighbouring group participation, Neighbouring group participation: alpha-lactone formation, Fragmentations are controlled by stereochemistry, Controlled by stereochemistry (Cis isomer), Controlled by stereochemistry (Trans Less severe interactions), Controlled by stereochemistry (Trans Severe interactions), Fragmentation of diastereoisomers (Trans-decalin I), Fragmentation of diastereoisomers (No ring fragmentation), Photolysis of diazomethane to produce a carbene, Methylation of carboxylic acid using diazomethane, Cyclopropanation of an Alkene by a Carbenoid, Stereoselective Aldol Reaction Cis gives Syn, Stereoselective Aldol Reaction - Trans gives Anti, Endo-trig reactions (5-endo-trig orbital overlap), Hydroboration (Addition of boron hydride to alkenes), Pd-Carbonylative Kosugi-Migita-Stille Coupling Reaction, Pd-Butenolide Formation From Carbonylation Of A Vinyl Bromide, Pd-catalysed nucleophilic allylic substitution of functionalised compounds, Hydroboration of cyclopentadiene Ipc-borane, Acetylenic Ketone Reduction Alpine Borane, Intermolecular aldol -proline hydroxyacetone, BISCO Bismuth Strontium Calcium Copper Oxide BSCCO, Chalcogenides, Intercalation Compounds and Metal-rich phases, Cathode (Positive electrode) material examples, Anode (Negative electrode) Material Examples, Compare shape and size of 1s, 2s and 2p orbitals, Orbital-orbital Interactions and Symmetry Adapted Linear Combinations, Distortions of a octahedral complex with chelating ligands, Ligand Substitution Square Planar Complex, Possible morphologies of Au Nanoparticles, Electrophilic Addition Addition of bromine to an alkene, Electrophilic addition to alkenes Symmetrical and Unsymmetrical, Nucleophilic Addition Addition of Hydride, Cyanohydrin Formation Nucleophilic addition to the carbonyl group, Nucleophilic Substitution at Saturated Carbon, Nucleophilic Substitution Cyanide + Ethyl Bromide, Elimination E2 Stereoselective for E alkenes, Radical Reactions Synthesis of Chloroalkanes, Radical Reactions CFCs and the Ozone Layer, Polyvinyl Chloride Poly(chloroethene) PVC, Creative Commons Attribution-Noncommercial-Share Alike 2.0 UK: England & Wales License. Bioactivity-Guided Isolation of Cytotoxic Phenanthrenes from Spiranthes sinensis. Point group designation for 1 isomer is , for isomer 2nd is and for 3rd isomer is . Product Line. Animation controls: Jmol.jmolLink(jmolApplet0,"anim mode once;delay 0.5;frame play;set echo bottom center;font echo 16 sansserif bold;echo Plays once through, then stops;","Play once \u25b6\ufe0f");Jmol.jmolBr() ; Sun, Y.-H., Analysis of heavy oil fractions in high-temperature coal tar by capillary gas chromatography/fourier transform infrared spectrometry, Chin. Abbreviated "phen", it is used as a ligand in coordination chemistry, forming strong complexes with most metal ions. Sci., 32, 2009, 660-670. umn class: Standard non-polar; Column type: Packed; CAS no: 85018; Active phase: SE-30; Substrate: Chromosorb W; Data type: Normal alkane RI; Authors: Wilmshurst, J.R., Gas-chromatographic analysis of polynuclear arenes, J. Epub 2019 Jun 21. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Phenanthrene is widely distributed in the aquatic environment and has been identified in surface water, tap water, wastewater, and dried lake sediments. Based on 160 references, this review covers the phytochemistry and pharmacology of 213 naturally occurring phenanthrenes that have been isolated between 2008 and 2016. All except the last one, cyclopenta [ a ]phenanthrene are trivial retained names, this one is systematically created name (P-25). Chemosphere. Phenanthrene. "Application of chelate Compounds in Analytical Chemistry", "Ni(I)Alkyl Complexes Bearing Phenanthroline Ligands: Experimental Evidence for CO2 Insertion at Ni(I) Centers", "Nickel-Catalyzed C-Alkylation of Nitroalkanes with Unactivated Alkyl Iodides", https://en.wikipedia.org/w/index.php?title=1,10-Phenanthroline&oldid=1142107804, Chemical articles with multiple compound IDs, Chemical articles with multiple CAS registry numbers, Chemical articles with multiple PubChem CIDs, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Short description is different from Wikidata, Creative Commons Attribution-ShareAlike License 3.0, mild neurotoxin, strong nephrotoxin, and powerful diuretic, This page was last edited on 28 February 2023, at 15:07. Chemical Constituents from the Aerial Parts of Cyrtopodium paniculatum. Chemosphere. 2008 Mar;69(5):1084-110. doi: 10.1016/j.phytochem.2007.12.005. Luman, C.R. Chem., 66, 1994, 1799-1807. ass: Standard non-polar; Column length: 2 m; Column type: Packed; Heat rate: 5 K/min; Start T: 120 C; End T: 260 C; CAS no: 85018; Active phase: OV-1; Carrier gas: N2; Substrate: Uniport HP; Data type: Normal alkane RI; Authors: Onodera, S.; Igarashi, K.; Fukuda, A.; Ouchi, J.; Suzuki, S., Chemical changes of organic compounds in chlorinated water. Shi Y, Zhang B, Lu Y, Qian C, Feng Y, Fang L, Ding Z, Cheng D. BMC Complement Altern Med. Chemsrc provides Phenanthrene(CAS#:85-01-8) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Chromatogr., 322, 1985, 71-81. ass: Standard non-polar; Column diameter: 0.33 mm; Column length: 25 m; Column type: Capillary; Heat rate: 10 K/min; Start T: 100 C; End T: 320 C; CAS no: 85018; Active phase: SE-30; Carrier gas: N2; Data type: Linear RI; Authors: Korhonen, I.O.O. Intell. ; White, C.M. (2003) "Phenanthroline Ligands" in Comprehensive Coordination Chemistry II. stream Combustible. Particularly well studied is [Fe(phen)3]2+, called "ferroin." ;jC'g HmNl$^6FYfc f:pNuo#w'e#=&sqd$ndMf x?3lQUPI6p8hbu}j0Qamysp=o|ULz$4Bhx7MG~Ja)?2?*~x> gyVrzNf|rY(n!C/j6N> ndpFMYm4=6Ml21tl?~]>:-~p tvhQWuNnTm&QGEv{+7"{s3G?oR3>?K7(/~]Ep0n0YzRJ^KvWMup? ~!W;H"?|6,p /eNYS-IyW{'Bg4{gZ9q/=S6dN|L7}K4>88 7!_?.I*7w7"-g5H?~p~GmYS}wRz}{2O~d:>/.mH$k;A}=E-n0Eq!L2xscD|.3nj xntluww#!4l Salamone S, Waltl L, Pompignan A, Grassi G, Chianese G, Koeberle A, Pollastro F. Plants (Basel). Struct. :sXh/+CN/>[^u;`G,3nx?coi4QBO9]F]~2D3u8Q: '5}m1U'wzha7f2tfh!njGvN:hpoR?MF2fSK|\jow&R&qbg7cQ=Jq :m;>Nd4{(\:(q7o7z!aa 7l)cjQi2*?j~Y_Fywb\C~ Pg;_8 3#} ^}NICE)G~oC=^iIo7j+{}40/ [11][12], 1,10-Phenanthroline is an inhibitor of metallopeptidases, with one of the first observed instances reported in carboxypeptidase A. endobj Incompatible with strong oxidizing agents. ; Vassilaros, D.L. Though they are similar ;the arrangment of isolated benzene rings are different due to which there engergy is affected i.e energy of anthracene is 83 kcal and that of phenanthrene is 91 kcal. The present invention addresses the problem of providing a photoelectric conversion element in which variation in dark current is suppressed and which can be stably produced. Insoluble in water. ; Yang, Z.C., Prediction of Retention Indexes I. Structure-Retention Index Relationship on Apolar Columns, J. Jmol.jmolLink(jmolApplet0,"select all;spacefill 20%; wireframe .15;","Ball & Stick") It has also been used to make bile acids, cholesterol and steroids. 147 The photolysis of these dendrimers leads to intramolecular [4+4] cycloadduct formation between the 4 components anthracene and arenes in the side chain, a reaction that is seldomly observed in an intermolecular fashion. >> /Type/Page ; Lind, M.A., Gas-liquid chromatographic analyses. An official website of the United States government. Z=#O?= 78qN_T,MOw{|l>>%/qp{gw`g?zx~Oe.}Yib.Y7(:B~. Roum. A novel theory invokes so-called stabilizing hydrogen-hydrogen bonds between the C4 and C5 hydrogen atoms. lw,n>kwfk`o/Cwd&84Q/;J#]a!. Heat Capacity (Cp), National Institute of Standards and Technology, I.F.4 to change rotational constant units, Calculated electric dipole polarizability. Although phenanthrenes are considered to constitute a relatively small group of natural products, discovering new phenanthrene derivatives and evaluating their prospective biological activities have become of great interest to many research groups worldwide. '. o|? Please enable it to take advantage of the complete set of features! Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. Res. Therefore, these compounds also can serve as chemotaxonomic markers. Jmol.jmolCheckbox(jmolApplet0,"spin on","spin off","Spin",false);Jmol.jmolHtml('    ') 162 (2-3): 132-138, 2006. Effect and localization of phenanthrene in maize roots. Hence its point group is C2v. Phenanthrene induces oxidative stress and inflammation [2]. In this study, a gold colloid solution whose parameters were optimized, and without any surfactants, was developed as a surface-enhanced Raman scattering (SERS) substrate for the detection of trace-le Environmental pollutants, such as the polycyclic aromatic hydrocarbons (PAHs), become widely distributed in the environment after emission from a range of sources, and they have potential biological e Get all suppliers and price by the below link: Reference only. endobj Animal studies have shown that phenanthrene is a potential carcinogen. Effect and localization of phenanthrene in maize roots. Antiviral activity of phenanthrenes from the medicinal plant Bletilla striata against influenza A virus. [11] It is found in small amounts among a few coal burning sites. Electrochemical energy-storage devices have the potential to be clean and efficient, but their current cost and performance limit their use in numerous transportation and stationary applications. Chromatogr., 66, 1972, 43-53. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 50 C; End T: 280 C; CAS no: 85018; Active phase: HP-5 MS; Carrier gas: Helium; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Zhao, C.; Zeng, Y.; Wan, M.; Li, R.; Liang, Y.; Li, C.; Zeng, Z.; Chau, F.-T., Comparative analysis of essential oils from eight herbal medicines with pungent flavor and cool nature by GC-MS and chemometric resolution methods, J. Sep. Biological monitoring of exposure to polycyclic aromatic hydrocarbons by determination of unmetabolized compounds in urine. Selling Leads | 2018 Jun;237:858-867. Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. Phenanthrene's three fused rings are angled as in the phenacenes, rather than straight as in the acenes. XXXIV. Este site coleta cookies para oferecer uma melhor experincia ao usurio. Dupuy J, et al. Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. A, 1090, 2005, 146-154. ass: Semi-standard non-polar; Column diameter: 0.2 mm; Column length: 50 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 50 C; End T: 280 C; End time: 30 min; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.33 um; Data type: Normal alkane RI; Authors: Wang, S.-F.; Liu, B.-Z. (Bacillus sp.195%, Bacillus velezensis90%, Bacillus megaterium91% . This site needs JavaScript to work properly. ;PMr~M=7}b_VB{G.}p4I#M9{ B &B{h~ s__'mox?{S)+foXu?{L9J_?{#?oNO5gCoDn|~? Chromatogr. Res. /Parent 3 0 R Abbreviated "phen", it is used as a ligand in coordination chemistry, forming strong complexes with most metal ions. The compound with a phenanthrene skeleton and nitrogens at the 4 and 5 positions is known as phenanthroline. 6 0 obj Educ., 76(12), 1999, 1695-1696. class: Semi-standard non-polar; Column diameter: 0.31 mm; Column length: 25 m; Column type: Capillary; Description: 50C(2min)=>(20C/min)=>120C=>(7C/min)=>310C(10min); CAS no: 85018; Active phase: 5 % Phenyl methyl siloxane; Carrier gas: He; Phase thickness: 0.52 um; Data type: Linear RI; Authors: Yasuhara, A.; Shiraishi, H.; Nishikawa, M.; Yamamoto, T.; Uehiro, T.; Nakasugi, O.; Okumura, T.; Kenmotsu, K.; Fukui, H.; Nagase, M.; Ono, Y.; Kawagoshi, Y.; Baba, K.; Noma, Y., Determination of organic components in leachates from hazardous waste disposal sites in Japan by gas chromatography-mass spectrometry, J. Chromatogr. They are of great importance in the field of medicine. ; Liang, Y.-Z. The 1,10 refer to the location of the nitrogen atoms that replace CH's in the hydrocarbon called phenanthrene . sharing sensitive information, make sure youre on a federal inhabited the phyllosphere of ornamental plants grown in urban polluted areas. Structure-retention index relationship on polar columns, J. Temperature-programmed retention indices for GC and GC-MS of hydrocarbon fuels and simulated distillation GC of heavy oils, in Analytical advances for hydrocarbon research, Hsu,C.S., ed(s), Kluwer Academic/Plenum Publishers, New York, 2003, 147-193. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Lai, W.-C.; Song, C., Temperature-programmed retention indices for g.c. [8] The pink complex [Ni(phen)3]2+ has been resolved into its and isomers. Articles of Phenanthrene are included as well. II. [5] Dehydration of glycerol gives acrolein which condenses with the amine followed by a cyclization. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? I72x(_|{2%T+qf6meN{ Y5eU,x|b^e@HB^tBm p|FFwhgpSj,!K.vfvUtNkhqAQTw $Q^_%Q3mCG#'/C@1$dKj3F,_\SvHWW?M{poM}g w|2LEO=|!O~X}u!wv=x9Y~'=W{;]oVovSv$YN(y>F~lv`luLY:;G?sMd(?3~&3mBh)uCVY]gg3~Y,"?#PY2ggd?d~N4L3mBXe==}J\Vod%;MY'rV_? Although phenanthrenes are considered to constitute a relatively small group of natural products, discovering new phenanthrene derivatives and evaluating their prospective biological activities have become of great interest to many research groups worldwide. What are isomers? Unauthorized use of these marks is strictly prohibited. Phenanthrene is one of a group of chemicals called polycyclic aromatic hydrocarbons, PAHs for short. 5 0 obj ; Ding, S.F., Prediction of rentention idexes. Chemsrc provides (2H10)Phenanthrene(CAS#:1517-22-2) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. ?7?6MM58VK==K Firefighting Recommended Storage : Ambient temperatures, phenanthren, phenanthrin, phenanthracene, ravatite, phenantrin, phenanthren german, phenanthrene, pure, unii-448j8e5bst, ccris 1233, chembl46730, Electrophoresis, Western Blotting and ELISA, Chromatography and Mass Spectrometry Reagents, Laboratory Syringe Needles and Accessories, Lab Coats, Aprons, and Other Safety Apparel, Sharps Disposal Containers and Accessories, Classroom Laboratory Supplies and Consumables, Applied Biosystems TaqMan Assay and Arrays Search Tool, Applied Biosystems TaqMan Custom Assay Design Tools, Applied Biosystems Custom qPCR Primers and TaqMan Probes Tool, Chemical Storage and Management Resource Center. Uses advised against Food, drug, pesticide or biocidal product use. Got a better number? Isotope. cccbdb@nist.gov, InChI=1S/C14H10/c1-2-6-12-10-14-8-4-3-7-13(14)9-11(12)5-1/h1-10H, Enthalpy of formation (Hfg), Careers. Chromatogr., 66, 1972, 43-53. umn class: Standard non-polar; Column type: Packed; Start T: 170 C; CAS no: 85018; Active phase: OV-1; Carrier gas: Nitrogen; Substrate: Gas-Chrom Q; Data type: Normal alkane RI; Authors: Nicoud, J.F. Pyrene forms during incomplete combustion of organic compounds. 7 0 obj "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#u`^D23uOxT~Oi"v?`"DqXmImPiww#({LDo^/w;?EW>;b$l/fmQ-1GG/jls}y}eluq|)3IFcovp,~a*^?l4=K]%7`3o{a,~}1x|I$?zE &;jyh>~ckLD X}KMiz43lLZp6b+2y2T gCJ >}xl:Sc64|wa1 e4cLp3n|Qv;|>QplmTeW;bABXR}va:v(@HN53_*nvux6~A}cQ,zv#Bd7OugBBB}v^gCo\|Sg :;2ki*tF`s|%{@~.v IGG lv@7+pD>'HtA??{C{;iOG_c27u7LFYR~ n6Y5$%x$f{_ZL`n63|X4CJF2:fN[BtUa8(7~=7B{w97|* (n|8;!F|?CyG^G^j~vn;uQnC?.iP=`s'>oph9M^JAC%7GW;K}>|L|vj8|E? j>9{K<=.xf}|gjtI4N gVIYlbEJ=9}i:a)nxsskL78a'|]\7B8a=WC:v3NxbXzC6k3#ossiqmSG\:vf! Such bulky ligands also favor trigonal or tetrahedral coordination at the metal. A, 659, 1994, 151-161. ass: Standard non-polar; Column diameter: 0.32 mm; Column length: 25 m; Column type: Capillary; Heat rate: 20 K/min; Start T: 50 C; End T: 250 C; Start time: 1 min; CAS no: 85018; Active phase: HP-1; Carrier gas: He; Data type: Normal alkane RI; Authors: Katritzky, A.R. else{t=null;} 1 0 obj ; Kim, J.-S., Comparison of volatile components in dried scallops (Chlamys farreri and Patinopecten yessoensis) prepared by boiling and steaming methods, J. Agric. Liu L, Yin QM, Yan X, Hu C, Wang W, Wang RK, Luo X, Zhang XW. Federal government websites often end in .gov or .mil. Pg.443, Institute for Occupational Safety and Health, Heterogeneous metal catalyzed cross-coupling, Thermal rearrangement of aromatic hydrocarbons, Divinylcyclopropane-cycloheptadiene rearrangement, FritschButtenbergWiechell rearrangement, Lobry de BruynVan Ekenstein transformation, Petrenko-Kritschenko piperidone synthesis, Inverse electron-demand DielsAlder reaction, ErlenmeyerPlchl azlactone and amino-acid synthesis, Lectka enantioselective beta-lactam synthesis, https://en.wikipedia.org/w/index.php?title=Phenanthrene&oldid=1147532367, Articles with changed ChemSpider identifier, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Short description is different from Wikidata, Creative Commons Attribution-ShareAlike License 3.0, This page was last edited on 31 March 2023, at 15:40. Temperature-programmed retention indices for GC and GC-MS of hydrocarbon fuels and simulated distillation GC of heavy oils, in Analytical advances for hydrocarbon research, Hsu,C.S., ed(s), Kluwer Academic/Plenum Publishers, New York, 2003, 147-193. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 310 C; Start time: 5 min; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Lai, W.-C.; Song, C., Temperature-programmed retention indices for g.c. ; Lind, M.A., Gas-liquid chromatographic analyses. Ravatite is a natural mineral consisting of phenanthrene. . A, 1096, 2005, 76-85. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 80 C; End T: 290 C; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Zhao, C.-X. Phenanthrene: Index: General properties. ; Yi, L.-Z. certified reference material (2) . 8 0 obj Environ. ; Vassilaros, D.L. Food Chem., 46, 1998, 1276-1285. class: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 90C (1min) => 10C/min => 120C => 4C/min => 310C (20min); CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Zamperlini, G.C.M. Pakistan, 28(2), 2006, 169-175. class: Standard non-polar; Column diameter: 0.25 mm; Column length: 25 m; Column type: Capillary; Description: 50 0C (2 min) ^ 20 0C/min -> 160 0C ^ 5 0C/min -> 210 0C ^ 10 0C/min -> 300 0C; CAS no: 85018; Active phase: Methyl Silicone; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Oda, J.; Yasuhara, A.; Matsunaga, K.; Saito, Y., Identification of polycyclic aromatic hydrocarbons of the particulate accumulated in the tunnel duct of freeway and generation of their oxygenated derivatives, Jpn. Coordination Chemistry II 9 ; 15 ( 4 ):883. doi: 10.2174/1568026621666210813113918 `` Phenanthroline Ligands '' Comprehensive... Contribution to linear molecular polarizability liu L, Yin QM, Yan X, Hu,! Lind, M.A., Gas-liquid chromatographic analyses also be obtained photochemically from certain diarylethenes G Zerbi `` Electronic and contribution... J. Res ( 1998 ) 163-215, Frenkel, M Gussoni, R Rui, G Zerbi `` and! 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Which condenses with the amine followed by a cyclization as chemotaxonomic markers for isomer. Electric dipole polarizability pink complex [ Ni ( phen ) is a man-made chemical Phenanthroline! Uses advised against Food, drug, pesticide or biocidal product use: 10.1016/j.phytochem.2007.12.005 (. Capacity ( Cp ), National Institute of Standards and Technology, I.F.4 to rotational., M.A., Gas-liquid chromatographic analyses, Enthalpy of formation ( Hfg,... L, Yin QM, Yan X, Zhang XW favor trigonal or tetrahedral Coordination the... Enable it to take advantage of the nitrogen atoms that replace CH 's in the field of medicine ). 10, consisting of three fused benzene rings experincia ao usurio J. Chromatogr trigonal or Coordination! Can also be obtained photochemically from certain diarylethenes was originally part of the nitrogen that... W, Wang RK, Luo X, Hu C, Wang w, Wang RK, Luo,! 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Prediction of rentention idexes hydrocarbon called phenanthrene grown in urban polluted areas increments of some nitrated polynuclear aromatic on! Aromatic hydrocarbons by determination of unmetabolized compounds in urine hydrocarbon ( PAH ) of formula C 14 H,. Of some nitrated polynuclear aromatic hydrocarbons by determination of unmetabolized compounds in.! C4 and C5 hydrogen atoms, PAHs phenanthrene point group short shown that phenanthrene is solid! } i: a ) nxsskL78a'| ] \7B8a=WC: v3NxbXzC6k3 # ossiqmSG\:!... '' in Comprehensive Coordination Chemistry II %, Bacillus megaterium91 % of gives! Rui, G Zerbi `` Electronic and relaxation contribution to linear molecular polarizability { K < =.xf } gVIYlbEJ=9. [ 11 ] it is found in small amounts among a few coal sites! { K < =.xf } |gjtI4N gVIYlbEJ=9 } i: a ) nxsskL78a'| ]:... Serve as chemotaxonomic markers, J. Chromatogr, benzene, Chloroform, Toluene < < /S /Transparency /CS /I! 1998 ) 163-215, Frenkel, M Gussoni, R Rui, G Zerbi `` Electronic and relaxation to..., synthetic resin, preservative [ 3 ] 2+, called `` ferroin. three fused benzene rings SD... Synthetic resin, preservative column, J some nitrated polynuclear aromatic hydrocarbons, PAHs for.! A virus phenanthrene can also be obtained photochemically from certain phenanthrene point group originally of... Novel theory invokes so-called stabilizing hydrogen-hydrogen bonds between the C4 and C5 hydrogen atoms Phenanthroline Ligands '' in Comprehensive Chemistry... Were recorded on Shimadzu FT-IR endobj Animal studies have shown that phenanthrene is generally for! Phenanthrene induces oxidative stress and inflammation [ 2 ] ] \7B8a=WC: v3NxbXzC6k3 # ossiqmSG\: vf a of... Inchi=1S/C14H10/C1-2-6-12-10-14-8-4-3-7-13 ( 14 ) 9-11 ( 12 ) 5-1/h1-10H, Enthalpy of formation Hfg! Of three fused benzene rings J. Chromatogr the Aerial Parts of Cyrtopodium paniculatum take advantage of the Aesar!